Study on the intramolecular vibrational relaxation of h_2o and h_2o_2 H2O和H2O2分子内的振动弛豫
The intramolecular vibrational redistribution ( IVR) and the ultrafast solvent inertial relaxation should account for the faster decay, while the slower decay is attributed to the diffusive solvent relaxation. 快速弛豫过程来源于分子内振动能量再分配(IVR)和溶剂分子超快惯性弛豫动力学过程,而慢速弛豫过程对应于溶剂化的扩散分子弛豫动力学过程。